The first match by a Great Britain men's team for 41 years will be an Olympic warm-up game against Brazil at Middlesbrough on July 20, the Football Association have confirmed.
The match will see Stuart Pearce's side pitted against one of the favourites for the competition.
It will be part of a double-header at the Riverside Stadium with Team GB women's team, coached by Hope Powell, taking on Sweden before the men play Brazil.
A Great Britain team last played an international in an Olympic qualifier against Bulgaria in 1971, and have not played in an actual Games since 1960.
Team GB women are competing at their first Olympics and Powell